Review: Metode Analisis Senyawa Asam Benzoat dalam Produk Makanan dan Minuman
Abstract
Pengawet pangan menjadi hal yang penting seiring dengan meningkatnya sifat konsumerisme masyarakat. Salah satu contoh pengawet pangan adalah asam benzoat. Konsumsi asam benzoat dalam jumlah berlebih berbahaya bagi kesehatan. Berbagai metode analisis dengan spesifisitas dan selektivitas tinggi sangat dibutuhkan untuk pengujian kandungan asam benzoat dalam produk makanan dan minuman. Prosedur analisis perlu diperhatikan agar mampu menetapkan jumlah asam benzoat yang terdapat dalam produk pangan. Studi ini menyajikan tinjauan komprehensif tentang berbagai teknik analisis yang digunakan untuk analisis pengawet asam benzoat dalam produk pangan. Metode yang digunakan yaitu studi literatur terhadap jurnal nasional dan internasional yang membahas tentang metode analisis asam benzoat dalam produk pangan. Beragam prosedur analisis memiliki kelebihan dan kekurangan berdasarkan kondisi sampel yang akan dianalisis. Berbagai metode preparasi sampel yang telah dilakukan meliputi ekstraksi cair – cair, filtrasi membran, dan ultrasonik. Metode analisis asam benzoat yang telah digunakan yaitu spektrofotometri UV-Vis, Kromatografi Gas, dan Kromatografi Cair Kinerja Tinggi. Metode analisis RP-HPLC dengan detektor UV-Vis merupakan metode yang paling banyak digunakan dalam analisis asam benzoat.
Keywords
Full Text:
PDFReferences
Seetaramaiah K, A. Anton Smith, R.Murali RM. Preservatives in Food Products. Int J Pharm Biol Arch. 2011;2(2):583–99.
Kusi JK J, Acquaah SO. Levels of Benzoic Acid in Soft Drinks and Fruit Juices in Ghana. IOSR J Environ Sci Toxicol Food Technol. 2014;8(12):36–9.
Kemenkes. Farmakope Indonesia. V. Jakarta: Kementerian Kesehatan Republik Indonesia; 2014.
Joye I. Acids and Bases in Food. Ref Modul Food Sci. 2018;
Heydari R, Mousavi M. Simultaneous Determination of Saccharine, Caffeine, Salicylic Acid And Benzoic Acid in Different Matrixes By Salt And Air-Assisted Homogeneous Liquid-Liquid Extraction And High-Performance Liquid Chromatography. J Chil Chem Soc. 2016;61(3):3090–4.
Xu C, Liu J, Feng C, Lv H, Lv S, Ge D, et al. Investigation of Benzoic Acid and Sorbic Acid in Snack Foods in Jilin province, China. Int J Food Prop. 2019;22(1):670–7.
BPOM. Peraturan Badan Pengawas Obat dan Makanan Nomor 11 Tahun 2019 tentang Bahan Tambahan Pangan. Jakarta: Badan Pengawas Obat dan Makanan; 2019.
Hartwig A. Benzoic Acid and Alkali Benzoates [MAK Value Documentation, 2017]. Vol. 3, The MAK-Collection for Occupational Health and Safety. 2018. 1758–1828 p.
Hassan MM, Elrrigieg MAA, Sabahelkhier M, Idris. O. Impacts of The Food Additive Benzoic Acid on Liver Function of Wistar Rats. Int J Adv Res. 2016;4(8):568–75.
Dzieciol, Alicja Wodnicka, Elzbieta Huzar M. Determination of Benzoic and Sorbic Acid in Foods. Ecol Chem Eng A. 2012;19(4):451–6.
Yildiz A, Erdogan S, Saydut A, Hamamci C. High-Performance Liquid Chromatography Analysis and Assessment of Benzoic Acid in Yogurt, Ayran, and Cheese in Turkey. Food Anal Methods. 2012;5(3):591–5.
Visscher F, Gaakeer WA, Granados Mendoza P, De Croon MHJM, Van Der Schaaf J, Schouten JC. Liquid-liquid Extraction Systems Of Benzoic Acid In Water and Heptane, Methylbenzene, Or Trichloroethylene As Cosolvent. J Chem Eng Data. 2011;56(9):3630–6.
Kokya TA, Farhadi K, Kalhori AAM. Optimized Dispersive Liquid-Liquid Microextraction and Determination of Sorbic Acid and Benzoic Acid in Beverage Samples by Gas Chromatography. Food Anal Methods. 2012;5(3):351–8.
Abedi AS, Mohammadi A, Azadniya E, Mortazavian AM, Khaksar R. Simultaneous Determination of Sorbic and Benzoic Acids in Milk Products Using an Optimised Microextraction Technique Followed by Gas Chromatography. Food Addit Contam - Part A Chem Anal Control Expo Risk Assess. 2014;31(1):21–8.
Javanmardi F, Nemati M, Ansarin M, Arefhosseini SR. Benzoic and Sorbic Acid in Soft Drink, Milk, Ketchup Sauce and Bread by Dispersive Liquid–Liquid Microextraction Coupled With HPLC. Food Addit Contam Part B Surveill. 2015;8(1):32–9.
Jurcovan MM, Diacu E, Ene CP. Quantification of The Analytical Parameters and Uncertainty Budget For Traceable Measurements of Benzoic Acid in Soft Drinks By HPLC Method. UPB Sci Bull Ser B Chem Mater Sci. 2012;74(1):97–108.
Ding M, Peng J, Ma S, Zhang Y. An Environment-Friendly Procedure For The High Performance Liquid Chromatography Determination of Benzoic Acid And Sorbic Acid In Soy Sauce. Food Chem [. 2015;183:26–9.
Guarino C, Fuselli F, Mantia A La, Longo L. Development of an RP-HPLC Method For The Simultaneous Determination of Benzoic Acid, Sorbic Acid, Natamycin and Lysozyme in Hard And Pasta Filata Cheeses. Food Chem. 2011;127(3):1294–9.
Wati WI, Guntarti A. Penetapan Kadar Asam Benzoat dalam Beberapa Merk Dagang Minuman Ringan Secara Spektrofotometri Ultraviolet. Pharmaciana. 2012;2(2).
Skoog, DA., James, F., and Stanley R. Principles of Instrumental Analysis. Sixth. Canada: Thomson Brooks/Cole; 2007.
Sen I, Shandil A, Shrivastava VS. Determination of Benzoic acid Residue from Fruit Juice by Gas Chromatography with Mass Spectrometry Detection Technique. Arch Appl Sci Res. 2011;3(2):245–52.
Ahuja and Dong M. Handbook of Pharmaceutical Analysis by HPLC. Sixth. Amsterdam: Elsevier Academic Press; 2005.
Sanjaya R, Oktavia B. Analisis Kadar Asam Askorbat dan Asam Benzoat dalam Minuman Ringan dengan HPLC Menggunakan Fasa Gerak Metanol dan Buffer Asetat. 2012;1(2):42–6.
Hayun H, Harahap Y, Azizah CN. Penetapan Kadar Sakarin, Asam Benzoat, Asam Sorbat, Kofeina, dan Aspartam di Dalam Beberapa Minuman Ringan Bersoda Secara Kromatografi Cair Kinerja Tinggi. Maj Ilmu Kefarmasian. 2004;1(3):148–59.
Ling DS, Xie HY, He YZ, Gan WE, Gao Y. Determination of Preservatives by Integrative Coupling Method of Headspace Liquid-Phase Microextraction and Capillary Zone Electrophoresis. J Chromatogr A. 2010;1217(49):7807–11.
DOI: https://doi.org/10.33085/jdf.v5i2.4834
Refbacks
- There are currently no refbacks.
Sponsored/Supported by:
Contact Person:
Jl. Kapt Sumarsono 107, Helvetia, Medan, Sumatera Utara-20124, Indonesia
Hp: +6281262445695. Tel: (061) 42084606